A Dysprosium Metallocene Single-Molecule Magnet Functioning at the Axial Limit
نویسندگان
چکیده
منابع مشابه
A hydride-ligated dysprosium single-molecule magnet.
An experimental and ab initio computational study of an unsymmetrical, hydride-bridged di-dysprosium single-molecule magnet is reported.
متن کاملA carbon-rich ruthenium decorated dysprosium single molecule magnet.
The association of a carbon-rich ruthenium complex with an anisotropic dysprosium ion leads to a unique complex showing SMM behaviour with multiple relaxation processes.
متن کاملCoordination-perturbed single-molecule magnet behaviour of mononuclear dysprosium complexes.
By changing the ratio of reactants, two mononuclear Dy complexes, [Dy(phen)(acac)(3)] (1) and [Dy(phen)(2)(NO(3))(2)(acac)]·H(2)O (2) have been synthesized and structurally characterized. In 1, a Dy atom bearing square-antiprism coordination geometry exhibits SMM behaviour, while compound 2 with a bicapped-square-antiprism geometry does not show such SMM properties. The different magnetic behav...
متن کاملDysprosium Acetylacetonato Single-Molecule Magnet Encapsulated in Carbon Nanotubes
Dy single-molecule magnets (SMMs), which have several potential uses in a variety of applications, such as quantum computing, were encapsulated in multi-walled carbon nanotubes (MWCNTs) by using a capillary method. Encapsulation was confirmed by using transmission electron microscopy (TEM). In alternating current magnetic measurements, the magnetic susceptibilities of the Dy acetylacetonato com...
متن کاملEmployment of triketones to construct a dysprosium(III) single-molecule magnet.
The initial employment of a triketone ligand in 4f coordination chemistry afforded a series of dinuclear complexes. Magnetic studies revealed that an antiferromagnetic interaction exists in a digadolinium(III) compound, while a dysprosium(III) constructed complex exhibits single-molecule magnet (SMM) behaviour at low temperatures with an energy barrier of 86.8 K.
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Angewandte Chemie
سال: 2017
ISSN: 0044-8249
DOI: 10.1002/ange.201705426